Physical Chemistry

ENBE600007

Prerequisites

–

Course Type

Compulsory

Credit Hours

3

Course Learning Outcomes

  • Apply basic principles, laws, and theories related to gases, liquids, equilibrium, and solutions to solve problems in physical chemistry.
  • Solve problems collaboratively in working groups by following structured problem-solving stages.

Course Content / Syllabus

  • The Nature of Gases and Liquids

    • Definition and properties of gases and liquids
    • Laws of ideal and real gases
    • Applications of gas laws
    • Gas kinetic theory (velocity, collisions, mean free path)
    • Phase diagrams and critical conditions
    • Viscosity of gases and liquids
  • Chemical Reaction Equilibrium

    • Definition of chemical equilibrium
    • Homogeneous and heterogeneous equilibrium constants
    • Factors affecting equilibrium (Le Chatelier’s principle)
    • Effect of pressure and temperature on equilibrium constants
  • Ideal Solutions

    • Definition and types of solutions
    • Concentration and solution properties
    • Raoult’s law and Henry’s law with case examples
    • Partial molar volume and colligative properties:
      • Vapor pressure
      • Boiling point elevation
      • Freezing point depression
      • Osmotic pressure
  • Electrolyte Solutions

    • Definition and colligative properties of electrolyte solutions
    • Electrolytic conductance and factors affecting it
    • Ion migration, Hittorf’s law, and transport numbers
    • Case examples and applications
  • Chemical Reaction Kinetics

    • Basic concepts and reaction orders (first, second, third)
    • Reversible, parallel, and consecutive reactions
    • Chain reactions and Arrhenius equations
    • Activation energy and collision theory
    • Transition state theory of bimolecular reactions
  • Surface Phenomena

    • Surface tension and adsorption (monolayer and multilayer)
    • Catalytic reaction kinetics and reaction order
    • Heterogeneous reactions and the effect of temperature
    • Catalytic inhibitors and their mechanisms

Recommended References

  1. Levine, I. N., Physical Chemistry, 6th ed., McGraw-Hill, 2008.
  2. Atkins & de Paula, Atkin’s Physical Chemistry, 9th ed., Oxford University Press, 2009.